کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
53314 | 46962 | 2016 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Selective cyclohexane oxidation catalyzed by manganese porphyrins and co-catalysts
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Selective cyclohexane oxidation catalyzed by manganese porphyrins and co-catalysts Selective cyclohexane oxidation catalyzed by manganese porphyrins and co-catalysts](/preview/png/53314.png)
چکیده انگلیسی
• Catalytic activity of co-catalysts is found to be closely related to the polarity.
• High selectivity of products in the cyclohexane oxidation is achieved.
• We report a new approach for preparing glutaric acid.
Several polar molecules, such as alcohols, ketones, esters and acids, were used as co-catalysts for the cyclohexane oxidation catalyzed by manganese porphyrins, and the catalytic activity was found to be closely related to polarity of co-catalysts. The results indicated that the total selectivity of products was as high as 96.3% and glutaric acid selectivity was up to 50.9%. Thus, the proposed method provides a new approach for preparing glutaric acid.
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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Today - Volume 264, 15 April 2016, Pages 185–190
Journal: Catalysis Today - Volume 264, 15 April 2016, Pages 185–190
نویسندگان
Tao Wang, Yuanbin She, Haiyan Fu, Hui Li,