کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5348424 1388079 2015 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Active site of bimetallic heterogeneous catalyst by atomic resolution aberration-corrected STEM
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Active site of bimetallic heterogeneous catalyst by atomic resolution aberration-corrected STEM
چکیده انگلیسی
The localized defect of Au-Pd bimetallic heterogeneous nanoparticles catalyst was investigated using HRTEM and aberration-corrected HRSTEM. The phase plates were calculated from the aberration coefficients of the measured probe tableau for various outer tilt angle of the optical axis and the accuracy required for the compensation of the various residual aberration coefficients in order to achieve sub-angstrom resolution with the electron optics system was evaluated up to the fifth order aberrations. It is found that the interplanar spacing of the Au-Pd nanoparticle (1 1 1) planes observed along the [1 1 0] zone axis was approximately 0.24 nm measured by HRTEM. In addition, the HRSTEM HAADF image demonstrated that the twin boundaries on the surfaces of heterogeneous nanoparticles catalysts at atomic scale. These defects might be introduced during the growth to alleviate the internal stress caused by the 4.6% lattice mismatch of Au-Pd bimetallic system. Current research could be applied to the study of active sites in nanocatalysts.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 354, Part A, 1 November 2015, Pages 129-133
نویسندگان
, ,