کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5348890 | 1503609 | 2015 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Size-dependent of chromium (VI) adsorption on nano α-Fe2O3 surface
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
Cr (VI), which had a strong oxidation ability and migration capability, was one of the major metal pollutants in the water resources. Hematite nanoparticles, which acted as a kind of environmental repair material, could be used to deal with the metal ions contamination. In this paper, four different sizes of nanoparticles hematite were synthesized by sol-gel method and the samples were characterized by XRD, SEM, etc. The adsorption effect and structure were studied, respectively, by ICP and infrared spectrum. The mechanism of Cr (VI) adsorption on the surface of nano hematite was also discussed. We found that Cr (VI) adsorption on hematite in water has size dependence. Cr (VI) was most likely bound to the sites of water adsorption on the surface of hematite, and as a result, forming complex structure with the surface of hydroxylation hematite. Cr (VI) may be also directly adsorbed on the surface of hematite replacing the binding sites of OH.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 356, 30 November 2015, Pages 18-23
Journal: Applied Surface Science - Volume 356, 30 November 2015, Pages 18-23
نویسندگان
Qing Xiao, Ying Sun, Jing Zhang, Qiuju Li,