کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5348944 | 1503609 | 2015 | 38 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of NaOH molar concentration on optical and ferroelectric properties of ZnO nanostructures
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The present study reports the effects of NaOH concentrations in hydrothermally grown ZnO nanostructures on structural, optical and ferroelectric properties at different selected NaOH molar concentrations (3-7Â M). X-ray diffraction, Raman and photoluminescence analysis confirms the formation of pure phase of ZnO. FESEM images show that the average grain size of ZnO nanostructures increases from 61 to 95Â nm as molar concentration increases from 3 to 7Â M, respectively. Transmission electron microscope analysis also reveals that an average grain size of ZnO nanostructures increases from 34 to 55Â nm as molarity increases from 3 to 7Â M concentrations. A significant reduction in the optical band gap is observed from 4.41 to 3.96Â eV by increasing molar concentration from 3 to 7Â M, respectively. The decrease in the band gap with molar concentration could be due to the increase of density of localize state in the conduction band. Furthermore, ferroelectricity is observed in ZnO nanostructures at room temperature which is interesting and adds an additional dimension to its applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 356, 30 November 2015, Pages 438-446
Journal: Applied Surface Science - Volume 356, 30 November 2015, Pages 438-446
نویسندگان
Prakash Chand, Anurag Gaur, Ashavani Kumar, Umesh Kumar Gaur,