کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5350052 | 1503656 | 2014 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Chemically anchoring of TiO2 coating on OH-terminated Mg3(PO3)2 surface and its influence on the in vitro degradation resistance of Mg-Zn-Ca alloy
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Surface treatment is of particular interest to slow down the in vitro degradation of Mg-based implants. In this work, micro arc oxidation (MAO) coating was fabricated on Mg-Zn-Ca alloy which has been developed by our group especially for the application of bio-implants. Evident improvement in corrosion resistance was obtained although the MAO coating was porous. In order to further diminish the contact with SBF, a composite coating was prepared by introducing a TiO2 layer by liquid phase deposition (LPD) method on the MAO pre-treated alloy. The coatings were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR). The results of the potentiodynamic polarization experiments showed that, compared with the bare alloy, the corrosion potential of TiO2/MAO/alloy increased from â1.771 to â1.607Â V. At the same time, the corrosion current density decreased from 1.43Â ÃÂ 10â4Â AÂ cmâ2 to 5.69Â ÃÂ 10â7Â AÂ cmâ2. The improvement of degradation resistance in SBF was ascribed to both barrier effect and enhanced interface condition. The OH-terminated MAO layer surface can make the TiO2 layer anchor tightly on the MOA surface. The chemical bonding of composite layer induced by Mg2+ cations bridges was also analyzed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 308, 30 July 2014, Pages 38-42
Journal: Applied Surface Science - Volume 308, 30 July 2014, Pages 38-42
نویسندگان
Guoqin Cao, Lijie Wang, Zhenya Fu, Junhua Hu, Shaokang Guan, Caili Zhang, Liguo Wang, Shijie Zhu,