کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5353640 | 1503580 | 2016 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Surface, optical characteristics and photocatalytic ability of Scheelite-type monoclinic Bi3FeMo2O12 nanoparticles
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Bi3FeMo2O12 nanoparticles with the Scheelite-type monoclinic structure were prepared by the Pechini synthesis. The Bi3FeMo2O12 nanoparticle has a size of about 50Â nm. The phase formation and structural characteristic were studied by X-ray diffraction (XRD) patterns and Rietveld refinements. The Scheelite framework is characterized by a superstructure constructed by the ordered arrangement of Fe/Mo tetrahedral on the B sites. The surface characteristics of Bi3FeMo2O12 nanoparticles were studied by the measurements such as the scanning electron microscope (SEM), the transmission electron microscopy (TEM), and the N2-adsorption-desorption isotherm. Bi3FeMo2O12 nanoparticles present an efficient optical absorption in a wide wavelength region from UV to 540Â nm. The band gap energy was decided to be 2.3Â eV and characterized by a direct allowed electronic optical transition. The photocatalytic activity of Bi3FeMo2O12 nanoparticles was confirmed by the photodegradation of the rhodamine B (RhB) dye solution. The experiments indicate that the Scheelite-type molybdate could be a potential candidate of a visible-light-driven photocatalyst.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 387, 30 November 2016, Pages 351-357
Journal: Applied Surface Science - Volume 387, 30 November 2016, Pages 351-357
نویسندگان
Xinming Nie, Wumitijiang Wulayin, Tingting Song, Minxiao Wu, Xuebin Qiao,