کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5355388 | 1503578 | 2016 | 41 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Promotional mechanism of propane on selective catalytic reduction of NOx by methane over In/H-BEA at low temperature
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
Effects of propane/methane ratios on NOx reduction by mixtures of methane and propane over In/H-BEA catalyst were investigated at temperatures ranging from 250 to 550 °C. The higher catalytic activity of In/H-BEA was exhibited for CH4-SCR at high temperatures above 450 °C, while the higher NOx conversion was achieved in C3H8-SCR at below 425 °C. A broadened temperature window and enhanced CO2 selectivity were achieved by combining of methane and propane as the co-reductant. The mixtures with propane/methane of 1/2 showed the most superior T50 (325 °C) and T90 (500 °C) temperatures for NOx reduction over In/H-BEA catalyst. For the promotion mechanism of propane on NO reduction by methane at low temperature, the formation of carbonaceous species (e.g. R-COOH) were enhanced by the activation of C3H8 on Brønsted acid sites at low temperature, and further promoted the generation of NCO species, which was a crucial determining step for NO reduction.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 390, 30 December 2016, Pages 608-616
Journal: Applied Surface Science - Volume 390, 30 December 2016, Pages 608-616
نویسندگان
Hua Pan, Yanfei Jian, Yanke Yu, Ningna Chen, Chi He, Cheng He,