کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5359723 | 1503681 | 2013 | 27 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Impacts of different polymer binders on electrochemical properties of LiFePO4 cathode
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Impacts of different polymer binders (PVdF, PAA and PMMA) on electrochemical performance of the LiFePO4 cathode in Li-ion batteries are investigated. From CV result, the voltage between redox peaks of the LiFePO4 with PVdF, PAA and PMMA binders are 0.26, 0.20 and 0.23 V, respectively. The current of the LiFePO4 with PMMA binder shows the highest value of 1.4 mA. The apparent diffusion coefficient of the LiFePO4 with PVdF, PAA and PMMA binders is 8.30 Ã 10â12, 2.57 Ã 10â11 and 9.13 Ã 10â11 cm2 sâ1, respectively. The discharge capacities of the LiFePO4 with PVdF, PAA and PMMA binders are 106, 143 and 154 mAh gâ1 at an initial cycle, respectively. FE-SEM studies clearly demonstrate that plate-like PAA and PMMA coating on the electrodes form a protective film, which may decrease the amount of the deposits, thus decreasing crack and crystallization on the electrode surface. Achieved results indicate that PVdF, PAA and PMMA binders show better properties than the traditional one, especially PMMA one.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 282, 1 October 2013, Pages 444-449
Journal: Applied Surface Science - Volume 282, 1 October 2013, Pages 444-449
نویسندگان
Van Hiep Nguyen, Wan Lin Wang, En Mei Jin, Hal-Bon Gu,