کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5362407 | 1388284 | 2008 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Facile synthesis and characterization of acid-base bifunctionalized mesoporous silica
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
A simple acid-base bifunctionalized approach has been developed through grinding the precursors, magnesium and aluminium nitrates, with the as-prepared SBA-15, and then the generation of acid-base active sites and removal of host template were combined into a single step in the subsequent calcination procedure. A series of acid-base bifunctional mesoporous materials MgO-Al2O3-SBA-15 (MA-SBA-15) have been successfully synthesized by means of this approach. X-ray diffraction (XRD), high-resolution transmission electron microscopes (HRTEMs), N2 adsorption, FT-IR spectra, 27Al and 29Si magic-angle-spinning (MAS) NMR, NH3- and CO2-temperature programmed desorption (TPD), pyridine adsorption were employed to characterize the resultant mesoporous materials. The results indicate that the guests can be well dispersed in the channel of SBA-15, and the resultant materials exhibit excellent acid-basic properties with well mesoporous backbone, which make it possessing high activity for the synthesis of ethyl methyl carbonate, an important asymmetric carbonate ester compound.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 254, Issue 18, 15 July 2008, Pages 5967-5974
Journal: Applied Surface Science - Volume 254, Issue 18, 15 July 2008, Pages 5967-5974
نویسندگان
Ying Chen, Jinyu Han, Haitao Zhang,