کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5363691 | 1388304 | 2011 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: In situ X-ray photoelectron spectroscopy characterization of Al2O3/GaSb interface evolution In situ X-ray photoelectron spectroscopy characterization of Al2O3/GaSb interface evolution](/preview/png/5363691.png)
GaSb(0 0 1) was treated with (NH4)2Sx and the evolution of the interfacial chemistry was investigated, in situ, with monochromatic X-ray photoelectron spectroscopy (XPS), following heat treatment and exposure to trimethylaluminum (TMA) and deionized water (DIW) in an atomic layer deposition reactor. Elemental Sb (Sb-Sb bonding) as well as Sb3+ and Sb5+ chemical states were initially observed at the native oxide/GaSb interface, yet these diminished below the XPS detection limit after heating to 300 °C. No evidence of Ga-Ga bonding was observed whereas the Ga1+/Ga-S chemical state was robust and persisted after heat treatment and exposure to TMA/DIW at 300 °C.
⺠300°C annealing causes the O and S bonded to Sb to transfer to Ga ⺠300°C annealing causes leaves the top 5-6 nm of the substrate Sb rich ⺠TMA reduces the sulfur detected ⺠Sb-Sb, Sb-O and Sb-S bonds are not detected after annealing or ALD ⺠Ga-O and Ga-S remain detectable after annealing and ALD
Journal: Applied Surface Science - Volume 257, Issue 20, 1 August 2011, Pages 8747-8751