Synthesis of anatase TiO2 nanowires by modifying TiO2 nanoparticles using the microwave heating method

Anatase TiO2 nanowires with a diameter of 5-10 nm and length of 500 nm to 2 μm have been successfully synthesized by modifying TiO2 nanoparticles (P25) using the microwave heating method. The microwave power, reaction pressure, and reaction time for the synthesis of TiO2 nanowires were 500 W, 0.5-3.0 MPa (corresponding to a temperature range of 175-260), and 40-70 min, respectively. X-ray diffraction (XRD), field-emission scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and the BET techniques were used to investigate the phase structures, morphologies, and specific surface areas of the TiO2 nanowires. The effects of reaction time, pressure, and different post-treatment processes on the microstructures of TiO2 nanowires were discussed. It has been shown that the microwave heating method is efficient in transforming TiO2 nanoparticles to anatase TiO2 nanowires.

► Anatase TiO2nanowires with diameter of 5-10 nm have been synthesized by microwave heating method. ► The reaction condition was controlled at 500 W, 0.5- 3.0 Mpa, and 40- 70 min. ► The surface morphology, the structural and phase identification are investigated. ► The effects of reaction time, pressure, and different post treatments are discussed.