کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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5364168 | 1503700 | 2012 | 6 صفحه PDF | دانلود رایگان |
Anatase and rutile TiO2 composite nanopowders with different Fe-doped concentrations were synthesized by sol-gel technique. X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) were used to detect the crystalline structure and chemical state of the nanopowders. The photocatalytic activity was estimated by the degradation of 20Â mg/L methyl orange under an irradiation of 350-450Â nm light source. TiO2 powder with 28.76Â wt% rutile showed the highest degradation among the TiO2 composite powders, but the 1.0Â at% Fe-doping TiO2 with 20.64Â wt% rutile phase exhibited an even higher degradation than that without Fe doping. Doping of Fe in TiO2 composite powder induced an evident increase in absorption peak and a significant red-shift in absorption edge from 420Â nm to 460Â nm in UV-vis absorption spectrum, and these characteristics are responsible for the improvement of photocatalytic activity.
⺠Fe-doped dual-phase TiO2 powders were prepared by sol-gel route. ⺠The dual-phase TiO2 with 28.76 wt% rutile phase shows better photocatalytic activity. ⺠Fe doped dual-phase TiO2 exhibits the best photocatalytic activity among the tested TiO2. ⺠Fe doped dual-phase TiO2 powders show evident red-shift or decrease in band gap. ⺠A cooperated mechanism was proposed for the improved photocatalytic process.
Journal: Applied Surface Science - Volume 263, 15 December 2012, Pages 260-265