کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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5364578 | 1503702 | 2012 | 8 صفحه PDF | دانلود رایگان |
Here, we report some unique crystalline morphologies of poly(lactic acid) (PLA) via organic solvent-induced crystallization. It was revealed that the surface morphology of PLA can be fine tuned by simply varying the volume ratio of a mixed solvent (acetone/ethanol). By increasing the ethanol content in the mixed solvent, we observed a morphological evolution of PLA surface from spherulite to shish-kebab and bamboo-cage-like structure. It was also interesting to find that the initial surface structure of PLA plays an important role to determine the final solvent-induced crystalline morphology. This work provides a new method for manipulating PLA crystal morphology through a simple solvent-induced crystallization.
Highlights⺠PLA crystal morphologies can be tuned by adjusting acetone/ethanol ratio. ⺠Beautiful PLA shish-kebab crystals can be easily observed using SEM. ⺠Fractured surface is important for the morphological evolution of PLA surface.
Journal: Applied Surface Science - Volume 261, 15 November 2012, Pages 528-535