کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5365542 | 1388332 | 2007 | 6 صفحه PDF | دانلود رایگان |

In this paper, the effective method for nitrogen-doped TiO2âxNx photocatalyst coated on hollow glass microbeads is described, which uses titanium tetraisopropoxide [Ti(iso-OC3H7)4] as the raw materials and gaseous ammonia as a heat treatment atmosphere. The effects of heat treatment temperature and time on the photocatalytic activity of TiO2âxNx/beads are studied. The photocatalyst is characterized by the UV-vis diffuse reflection spectroscopy, X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRD), Brunauer-Emmett-Teller (BET) analysis and scanning electron microscopy (SEM). The results show that when the TiO2âxNx/beads is heated at 650 °C for 5 h, the photocatalytic activity of the TiO2âxNx/beads is the best. Compared with TiO2, the photoabsorption wavelength range of nitrogen-doped TiO2âxNx red shifts of about 60 nm, and the photoabsorption intensity increases as well. The photocatalytic activity of the TiO2âxNx/beads is higher than that of the TiO2/beads under visible light irradiation. The presence of nitrogen neither influences on the transformation of anatase to rutile, nor creates new crystal phases. When the TiO2âxNx/beads is heated at 650 °C for 5 h, the amount of nitrogen-doped is 0.53 wt.% in the TiO2âxNx. As the density of TiO2âxNx/beads prepared is lower than 1.0 g/cm3, it may float on water surface and use broader sunlight spectrum directly.
Journal: Applied Surface Science - Volume 253, Issue 6, 15 January 2007, Pages 3077-3082