Photocatalytic degradation of gaseous toluene on Fe-TiO2 under visible light irradiation: A study on the structure, activity and deactivation mechanism

The Fe-TiO2 photocatalysts synthesized by a sol-gel method have the mesoporous structure with a narrow pore size distribution, large pore volume and high surface area. The incorporated Fe3+ substitutes the octahedrally coordinated Ti4+ in the TiO2 lattice to extend the absorption of TiO2 to visible light region and promote the formation of electron-hole pair. Additionally, the separation and transportation efficiency increase with the doping of Fe3+ increasing from 0.1% to 0.7%, while decreases remarkably with the doping concentration increasing from 0.7% to 1.5%. The Fe-TiO2 shows excellent photocatalytic performance for toluene degradation under visible light irradiation. The optimal Fe/Ti ratio is 0.7%. Partial deactivation of the photocatalytic activity was observed after 20 consecutive reaction runs. From the in situ DRIFTS experiment, the deactivation reason can be attributed to the formation of stable intermediates, such as benzaldehyde and benzoic acid, which occupied the active sites on the surface of the photocatalyst. The adsorbed benzaldehyde and benzoic acid can be removed with heat treatment at 653 K for 3 h and the deactivated photocatalyst can be regenerated completely.

Highlights► The 0.7% Fe-TiO2 shows the best photocatalytic activity for gaseous toluene degradation under visible light irradiation. ► Different Fe3+ doping concentrations lead the differences in the electron-hole separation efficiency. ► Photocatalyst deactivation can be attributed to the occupancy of the active sites by the stable intermediates, benzaldehyde and benzoic acid.