کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5366024 1388342 2007 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Investigation of chemisorbed oxygen, surface segregation and effect of post-treatments on La0.8Sr0.2MnO3 powder and screen-printed layers for solid oxide fuel cell cathodes
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Investigation of chemisorbed oxygen, surface segregation and effect of post-treatments on La0.8Sr0.2MnO3 powder and screen-printed layers for solid oxide fuel cell cathodes
چکیده انگلیسی

In order to better understand the mechanism of the reaction of oxygen reduction at the surface of strontium doped lanthanum manganites (LSM) cathodes in solid electrolyte fuel cells (SOFC), the surface properties of La0.8Sr0.2MnO3 powders and screen-printed layers have been characterised by various techniques.Strontium enrichment at the surface has been evidenced by X-ray photoelectron spectroscopy according to the conditions of annealing (temperature, oxygen pressure) and polarisation treatments of the samples.The interaction between oxygen and La0.8Sr0.2MnO3 for SOFC cathodes has been studied by thermo-programmed desorption, in situ infrared spectrometry and calorimetry. The results indicate that various adsorbed oxygen species may exist on the surface of LSM depending on temperature.The presence of various adsorbed oxygen species and the surface Sr segregation are important factors to consider in the mechanism of oxygen reduction at LSM SOFC cathodes since they could be responsible for many discrepancies between the interpretations that can be found in the literature data.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 253, Issue 10, 15 March 2007, Pages 4641-4648
نویسندگان
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