Observation of ultra-long lifetime UV-induced infrared absorption in undoped and magnesium-doped congruent lithium niobate crystals

We report experimental observation of ultra-long lifetime UV-induced absorption in undoped and 5 mol.% Mg-doped congruent lithium niobate crystals between 400 nm and 2500 nm wavelength range. The saturated absorption coefficient change in undoped congruent lithium niobate was about 3 to 7 times that in Mg-doped congruent lithium niobate in the mid-infrared spectrum. The UV-illuminated LiNbO3:Mg was fully recovered in the dark after 2 days, whereas the undoped congruent LiNbO3 still exhibited nontrivial infrared absorption. We attribute the cause of the UV-induced absorption to the creation of hole-trapped intermediate states O− near lithium vacancies.

Research highlights► Observation of ultra-long lifetime UV-induced IR absorption in LiNbO3 and LiNbO3:Mg was reported. ► The saturated absorption coefficient change in undoped CLN was higher than that in CLN:Mg. ► UV-illuminated LiNbO3:Mg was fully recovered before undoped LiNbO3 in the dark after 2 days. ► UV-induced absorption was due to creation of hole-trapped intermediate states O− near Li vacancies.