کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5367874 | 1388376 | 2008 | 5 صفحه PDF | دانلود رایگان |
The interactions of gas phase oxygen with gadolinia-doped ceria (GDC) surfaces are investigated by electron stimulated desorption (ESD). The primary desorbed cationic species related to molecular oxygen adsorption is O2+. The threshold energy for ESD of O2+ is 13-14Â eV, indicating electron impact ionization of molecular oxygen bound at oxygen vacancies. Dependence of O2+ velocities upon incident electron energy and substrate temperature reveals the dominant influence of the effective charge of the adsorption complex. The O2+ velocity distribution is bimodal, and the onset of the faster components at room temperature is related to the balance between fluxes of incident electrons and secondary electron emission, causing effective hole production and neutralization of trapped electrons at surface states.
Journal: Applied Surface Science - Volume 254, Issue 16, 15 June 2008, Pages 4965-4969