کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5368054 | 1388383 | 2011 | 7 صفحه PDF | دانلود رایگان |
Both dimethylformamide (DMF) and diethylformamide (DEF) are important solvents for the synthesis of Zn4O(C8H4O4)3 framework (MOF-5). It is generally recognized that DMF molecules can be completely displaced by CH2Cl2 during the synthesis of MOF-5. Herein, however, it was found that the DMF molecules inside the pores of the MOF-5 framework cannot be displaced by CH2Cl2. The desorption of the DMF molecules from the pores, which requires a temperature of 100 °C or above, is the first order with activation energy of 56.38 kJ/mol. In contrast, DEF molecules can be completely displaced by CH2Cl2 during the synthesis of MOF-5, because DEF molecules cannot penetrate into the pores of the MOF-5 paste.
Research highlightsⶠDMF molecules inside the pores of the MOF-5 framework cannot be displaced by CH2Cl2. ⶠDesorption of the DMF molecules from the pores of MOF-5 framework requires a temperature of 100 °C or above. ⶠDesorption of the DMF molecules from the pores of the MOF-5 framework is the first order with activation energy of 56.38 kJ/mol. ⶠDEF molecules can be completely displaced by CH2Cl2 during the synthesis of MOF-5, because DEF molecules cannot penetrate into the pores of the MOF-5 paste.
Journal: Applied Surface Science - Volume 257, Issue 8, 1 February 2011, Pages 3392-3398