Etch front roughening in wrinkly metal

Scaling behavior of wrinkle evolution due to chemical etching of Au on stretchable substrate is studied by atomic force microscopy. The surfaces were etched with a small drop of KI solution. Scaling exponent α decreased with the etch time, from 0.93 to 0.62. For dynamic exponent β up to 30 min we find it to be 0.16 ± 0.05. Within the same time frame, the wavelength increases as ∼t0.23+−0.05 but drops at 45 min as ∼t−1.22+−0.42 and saturates. At this stage, we observe percolation island type features along with some wrinkles. The measured value of α at this stage is 0.62 ± 0.02; consistent with the percolation model. The wavelength coarsening at this stage suggests the existence of chemically driven spinodal decomposition. Our obtained value of α and β is consistent with the value of z obtained from correlation length which is given by ξ = t1/z. We find z = 4.87 ± 0.50. Our experiment suggests wrinkle formation in thin films on viscoelastic surface occurs in three stages.