Resonance enhanced multiphoton ionization time-of-flight (REMPI-TOF) study of phosphorous oxychloride (POCl3) dissociation at 235Â nm: Dynamics of Cl(2Pj) formation

► First results on dynamics of Cl atom formation in the photodissociation of POCl3. ► Two types of Cl atom formation mechanism. ► Cl2 formation from the ground state supported by ab initio calculation.