Electron transfer with TD-Split, a linear response time-dependent method

► Electron transmission from charged-dimer transition-state excitation. ► Starting point: extended dimer charged (above-gap) homo, which is then excited. ► Excitation by real-time and linear response TD propagation. ► Analogous to two level system, but with full polarization included. ► TD-Split much larger than from static LUMO + 1-LUMO splitting for fullerene dimers.