کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5374993 | 1504283 | 2010 | 13 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermally activated escape far from equilibrium: A unified path-integral approach
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
Thermally activated escape over potential barriers is addressed for systems driven out of equilibrium by time-dependent forces, temperatures, or dissipation coefficients of rather general type. Particular examples are periodic perturbations, single pulses, and the initial convergence towards Kramers rate in a time-independent set up. The general problem is treated within one common, unifying path-integral approach in the simplest case of an overdamped, one-dimensional model dynamics. As an application, the following quite astonishing effect is demonstrated: for a suitably chosen, but still quite simple static potential landscape, the net escape rate may be substantially reduced by temporally increasing the temperature above its unperturbed, constant level.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 375, Issues 2â3, 5 October 2010, Pages 386-398
Journal: Chemical Physics - Volume 375, Issues 2â3, 5 October 2010, Pages 386-398
نویسندگان
Sebastian Getfert, Peter Reimann,