کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5375451 | 1504296 | 2009 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Time resolved studies of decay of the XeI2(IP) complexes
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Results of the first studies of temporal behavior of luminescence in the λ = 235-275 nm and λ = 315-350 nm spectral ranges following optical-optical double resonance (OODR) excitation of I2 + Xe mixtures to the I2(f, vf = 9, Jf â 55) state as well as time-gated luminescence spectra measured with Ît = 10-70 ns time delay from the beginning of the laser probe pulse, I2(f,vf,JfâhvpB,vB,JB) have been described. The spectra look as quasi-continua superimposed with transition bands from the optically and collisionally populated I2(f, vf = 9, Jf â 55) and I2(F, vF = 1-11) states. The temporal histories of luminescence at the bands and quasi-continua differ significantly. It is shown that, to describe the quasi-continuum in the λ = 315-350 nm time-gated experimental spectra, transitions other than the I2(f, vf â B, vB) one have to be used. The I2(f and F) vibrational state distributions observed in experiments can be formed as result of predissociation of long-life XeI2(IP) complexes. The quasi-continuum in the λ â 330-350 nm spectral ranges can belong to the XeI2(f â B) transition.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 362, Issues 1â2, 30 July 2009, Pages 27-33
Journal: Chemical Physics - Volume 362, Issues 1â2, 30 July 2009, Pages 27-33
نویسندگان
M.E. Akopyan, S.S. Lukashov, Yu.D. Maslennikova, S.A. Poretsky, A.M. Pravilov,