کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5375668 | 1504301 | 2009 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A model for the multi-exponential excited-state decay of CdSe nanocrystals
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
We report on photoluminescence decay measurements of CdSe nanoparticles over several decades of intensities and times, and as a function of size and temperature. A model is proposed for the multi-exponential decay kinetics, and their temperature dependence, in which a major role is played by the now well established presence of a large ground-state dipole moment in CdSe nano crystals. By two-photon excitation within the bandgap region we show that there is a link between the ground-state dipole moment and the excited-state decay. The stochastic nature of the magnitude of the dipole moment results in a complex temperature dependence. Contrary to studies that ascribe non-radiative decay processes to surface states/traps, the mechanism we propose considers the intrinsic states described within the effective mass approximation models for the spectroscopy of the bandgap. Surface effects are mediated by the ground-state dipole moments that they constitute, which in turn perturb the intrinsic states.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 357, Issues 1â3, 23 February 2009, Pages 96-101
Journal: Chemical Physics - Volume 357, Issues 1â3, 23 February 2009, Pages 96-101
نویسندگان
A. Al Salman, A. Tortschanoff, G. van der Zwan, F. van Mourik, M. Chergui,