کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5376011 | 1504310 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Ground and excited state intramolecular proton transfer controlled intramolecular charge separation and recombination: A new type of charge and proton transfer reaction
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
A novel β-diketone 1-(4-(9-carbazol)phenyl)-3-phenyl-1,3-propanedione (CDBM) has been synthesized. When excited at 380 nm, this molecule shows single fluorescence. However, when excited at 338 nm, it shows dual fluorescence. A Al3+ complex Al(CDBM)3 has been synthesized to investigate the dual fluorescence of CDBM. It is found that this complex shows single fluorescence under all excitation. This result indicated that the dual fluorescence of CDBM may relate to the intramolecular proton transfer reaction. Based on the experimental and theoretical studies of CDBM, N-(4-cyanophenyl)carbazole (CBN) and Al(CDBM)3, a “ground and excited state intramolecular proton transfer controlled intramolecular charge separation and recombination” mechanism is proposed to explain the unusual excitation-dependent dual fluorescence of CDBM.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 348, Issues 1â3, 2 June 2008, Pages 181-186
Journal: Chemical Physics - Volume 348, Issues 1â3, 2 June 2008, Pages 181-186
نویسندگان
Daobo Nie, Zuqiang Bian, Anchi Yu, Zhuqi Chen, Zhiwei Liu, Chunhui Huang,