کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5376276 | 1504318 | 2007 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Matrix isolation infrared spectroscopic and theoretical study of noble gas coordinated dipalladium-dioxygen complexes
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The reaction products of palladium atoms with molecular oxygen in solid argon have been investigated using matrix isolation infrared absorption spectroscopy and quantum chemical calculations. In addition to the previously reported mononuclear palladium-dioxygen complexes: Pd(η2-O2) and Pd(η2-O2)2, dinuclear palladium-dioxygen complexes: Pd2(η2-O2) and Pd2(η2-O2)2 were formed under visible light irradiation and were identified on the basis of isotopic substitution and theoretical calculations. In addition, experiments doped with xenon in argon coupled with theoretical calculations suggest that the Pd(η2-O2), Pd2(η2-O2) and Pd2(η2-O2)2 complexes are coordinated by two argon or xenon atoms in solid argon matrix, and therefore, should be regarded as the Pd(η2-O2)(Ng)2, Pd2(η2-O2)(Ng)2 and Pd2(η2-O2)2(Ng)2 (NgAr or Xe) complexes isolated in solid argon.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 340, Issues 1â3, 9 November 2007, Pages 134-140
Journal: Chemical Physics - Volume 340, Issues 1â3, 9 November 2007, Pages 134-140
نویسندگان
Rui Yang, Yu Gong, Mingfei Zhou,