کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5376281 | 1504318 | 2007 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electron energy loss spectroscopy of liquid glycerol
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Electron energy loss spectroscopy of liquid glycerol Electron energy loss spectroscopy of liquid glycerol](/preview/png/5376281.png)
چکیده انگلیسی
The inelastic scattering of low energy electrons from liquid glycerol has been studied. For the first time, electron energy loss spectra of liquids are sufficiently well resolved to permit the identification of vibrations corresponding to individual bonds, namely the C-H and O-H stretching vibrations in glycerol. The angular distribution of the specular peak is very broad, indicating the absence of long-range order at the surface of the liquid. The measurement of the loss signals as a function of the primary electron energy suggests a hybrid mechanism of excitation. The excitation mechanism for the O-H vibration has a stronger impact character as compared to the C-H vibration. A negative ion resonance of glycerol is found at a primary energy of 8Â eV. The signal intensities measured as a function of the specular angle of the electron beam appear to be influenced by the angular dependence of the dipole and impact scattering cross-section and a possible preferred orientation of the C-H and O-H groups at the surface of the liquid.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 340, Issues 1â3, 9 November 2007, Pages 181-186
Journal: Chemical Physics - Volume 340, Issues 1â3, 9 November 2007, Pages 181-186
نویسندگان
Thomas Krebs, Gunther Andersson, Harald Morgner,