کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5376630 | 1504320 | 2007 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Vibrational coherences of the protonated Schiff base of all-trans retinal in solution
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
Modulations in the time gated ultrafast fluorescence of the protonated Schiff base of retinal in various solvents are reported, which reflect the creation and evolution of vibrational wave packets due to the torsional mode of retinal of frequency â¼120Â cmâ1. The oscillations are damped in â¼400Â fs. Their frequency is significantly decreased compared to the case of the protein (170Â cmâ1), and is insensitive to solvent properties such as the dielectric constant and the viscosity. This, along with previous results on mutants of bacteriorhodopsin, leads us to conclude that in the protein, the isomerization dynamics of retinal is governed by steric effects and by the inhomogeneous distribution of the electrostatic field due to amino-acid residues within the protein pocket. We also discuss the origin of the modulations and conclude that they are impulsively excited via the high frequency modes of retinal.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 338, Issues 2â3, 25 September 2007, Pages 168-174
Journal: Chemical Physics - Volume 338, Issues 2â3, 25 September 2007, Pages 168-174
نویسندگان
Goran ZgrabliÄ, Stefan Haacke, Majed Chergui,