کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5376708 | 1504329 | 2006 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Dielectric relaxation strength in ion conducting glasses caused by cluster polarization
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
A model for interpreting the dielectric relaxation strength Îε observed in ionic glasses is proposed. The model relates the dielectric strength to the polarization of nanometric structures formed by energetic clustering. The calculation of Îε relies exclusively upon equilibrium arguments, and its results are in agreement with previous derivations of the dc conductivity made from percolation approaches. The expression of Îε shows that its temperature and alkali content dependence is very sensitive to the underlying ion statistics so that no universal trend is expected. The model prediction is evaluated on the test case system of sodium conducting borate glass. The large variety in the dielectric strength dependences on modifier content is discussed in light of the inherent glassy structural complexity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 330, Issues 1â2, 8 November 2006, Pages 113-117
Journal: Chemical Physics - Volume 330, Issues 1â2, 8 November 2006, Pages 113-117
نویسندگان
Germà Garcia-Belmonte, François Henn, Juan Bisquert,