کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5376863 | 1504333 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Fragmentation of dimethyl ether in femtosecond intense field
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The fragmentation of dimethyl ether (DME) in intense femtosecond laser field has been studied at 810, 405 and 270Â nm with intensities up to 2.48Â ÃÂ 1015, 3.86Â ÃÂ 1015 and 1.62Â ÃÂ 1014Â W/cm2, respectively. At 405Â nm, DME is possibly firstly ionized by multiphoton absorption, and then parent ion DME+ dissociates into fragments via filed-induced dissociation. For 810 and 270Â nm laser fields, DME firstly dissociates into CH3O and CH3 fragments and then these neutral fragments are ionized by field tunneling. Another possible way for DME to dissociate at 810 and 270Â nm is that DME is ionized by intense field ejection of inner valance electron and then the excited DME+ dissociates into fragment ions. Ultrafast rearrangement of DME or DME+ in intense field may be responsible to the unpredictable fragment ions, CHO+/C2H5+andH2+.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 326, Issues 2â3, 1 August 2006, Pages 571-576
Journal: Chemical Physics - Volume 326, Issues 2â3, 1 August 2006, Pages 571-576
نویسندگان
Jingyi Zhu, Wei Guo, Yanqiu Wang, Li Wang,