کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5376983 1504334 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Near-contact adiabatic suppression of electron transfer in the inverted region
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Near-contact adiabatic suppression of electron transfer in the inverted region
چکیده انگلیسی
These changes affect significantly the spatial dependence of the transfer rate near the contact provided the coupling there is strong. The rate tends to zero at contact distance being strongly suppressed nearby adiabatically. It is much smaller then the perturbation (golden rule) and even DSE results. The latter is actually unattainable anywhere if contact tunneling is really strong. The transfer rate is a bell-shaped curve adiabatic and non-adiabatic on the opposite sides and sensitive to the friction (DSE damping) only in between, near the maximum.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 325, Issues 2–3, 20 June 2006, Pages 359-364
نویسندگان
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