کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5376997 | 1504334 | 2006 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Dependence with the oxidation state of X-ray transition energies, intensities and natural line widths of CrKβ spectra
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Dependence with the oxidation state of X-ray transition energies, intensities and natural line widths of CrKβ spectra Dependence with the oxidation state of X-ray transition energies, intensities and natural line widths of CrKβ spectra](/preview/png/5376997.png)
چکیده انگلیسی
Kβ1,3 line shifts in relation to metallic Cr were observed, both to higher energies (â
+1Â eV) for CrIII and to lower energies (â
â0.5 eV) for CrVI. It was also found that the natural width of CrKβ1,3 line, the ionization energy of the 3p orbital of Cr, and the relative intensities of KβⳠand Kβ2,5 lines with respect to the main Kβ1,3 line increase as the oxidation state increases. The use of these features as an index for chemical state analysis is discussed.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 325, Issues 2â3, 20 June 2006, Pages 477-484
Journal: Chemical Physics - Volume 325, Issues 2â3, 20 June 2006, Pages 477-484
نویسندگان
M. Torres Deluigi, G. Tirao, G. Stutz, C. Cusatis, J.A. Riveros,