کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5377164 | 1504336 | 2006 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electric properties of the azide ion calculated with a systematic sequence of Gaussian-type basis sets
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Electric properties of the azide ion calculated with a systematic sequence of Gaussian-type basis sets Electric properties of the azide ion calculated with a systematic sequence of Gaussian-type basis sets](/preview/png/5377164.png)
چکیده انگلیسی
We have designed a sequence of flexible Gaussian-type basis sets for electric property calculations on the azide ion. These basis sets range from [7s5p2d] to [7s5p5d3f2g] size. We have analyzed the performance of these basis sets on calculations of the quadrupole (Î), hexadecapole (Φ) moment, the mean (α¯) and the anisotropy (Îα) of the dipole polarizability at the self-consistent field (SCF), second-order Møller-Plesset perturbation theory (MP2) and B3LYP levels of theory. Our evaluation of the quality of these purpose-oriented basis sets bears on their overall performance on the {Î,Φ,α¯,Îα} collection of properties. Our best values for each property at MP2/[7s5p5d3f2g] are: Î=-8.5953ea02, Φ=-7.50ea04, α¯=41.74 and Îα=38.24e2a02Eh-1.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 323, Issues 2â3, 21 April 2006, Pages 451-457
Journal: Chemical Physics - Volume 323, Issues 2â3, 21 April 2006, Pages 451-457
نویسندگان
George Maroulis, Agesilaos Hatzis, Anastasios Haskopoulos,