کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5377346 | 1389386 | 2006 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
XAFS characterization of La1âxSrxMnO3±δ catalysts prepared by Pechini's method
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: XAFS characterization of La1âxSrxMnO3±δ catalysts prepared by Pechini's method XAFS characterization of La1âxSrxMnO3±δ catalysts prepared by Pechini's method](/preview/png/5377346.png)
چکیده انگلیسی
XAFS experiments at the Mn and Sr K-edges were carried out in order to investigate the short-range arrangement of Mn and Sr sites on La1âxSrxMnO3±δ highly doped perovskites (x = 0, 0.2, 0.4 and 0.6). The Mn K-edge EXAFS spectra show a static Jahn-Teller distortion of the MnO6 for x = 0 and 0.2, which is drastically reduced as x increases. The distortion of perovskite, characterized by the Mn-O-Mn tilt angle, progressively decreases with increasing Sr contents. Sr K-edge results indicated a decrease on the Sr-Mn coordination number upon Sr doping. Based on this and TPD results, a charge compensating mechanism is proposed suggesting a partial Mn oxidation and formation of Mn defect vacancies due to the introduction of Sr.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 322, Issue 3, 20 March 2006, Pages 477-484
Journal: Chemical Physics - Volume 322, Issue 3, 20 March 2006, Pages 477-484
نویسندگان
Dulce M.A. Melo, Filipe M.M. Borges, Renato C. Ambrosio, PatrÃcia M. Pimentel, Carlos N. da Silva Júnior, Marcus A.F. Melo,