کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5379950 | 1504883 | 2015 | 5 صفحه PDF | دانلود رایگان |
- Alcoholysis reactions of isocyanates are investigated using IR spectroscopy.
- Spectral changes are assigned with the help of anharmonic frequency calculations.
- Marker bands are monitored to extract data on reaction kinetics.
- Arrhenius activation energies between 3 and 7Â kcal/mol are observed.
The alcoholysis reaction of phenylisocyanate with cyclohexanol (I) and of 2,4-toluene-diisocyanate with chloraldhydrate (II) is studied by infrared absorption spectroscopy in combination with anharmonic frequency calculations using density functional theory. It is shown that the progress of the reaction can be monitored by measuring infrared marker bands in the isocyanate NCO and alcohol OH stretching regions. Analysis of spectra obtained as a function of time for different temperatures yields a second-order kinetics with an Arrhenius activation energy of 6.7 ± 0.2 and 2.8 ± 0.3 kcal/mol for reaction I and II, respectively.
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Journal: Chemical Physics Letters - Volume 621, 4 February 2015, Pages 41-45