کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5383836 1504979 2011 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
An experimental comparison of the Marcus-Hush and Butler-Volmer descriptions of electrode kinetics applied to cyclic voltammetry. The one electron reductions of europium (III) and 2-methyl-2-nitropropane studied at a mercury microhemisphere electrode
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
An experimental comparison of the Marcus-Hush and Butler-Volmer descriptions of electrode kinetics applied to cyclic voltammetry. The one electron reductions of europium (III) and 2-methyl-2-nitropropane studied at a mercury microhemisphere electrode
چکیده انگلیسی
► Experimental comparison between the Butler-Volmer and Marcus-Hush models is performed. ► The reductions of 2-methyl-2-nitropropane and Eu(III) at Hg microelectrodes are considered. ► Cyclic voltammetry reveals significant differences between models. ► Butler-Volmer adequately fits experimental data with consistent kinetic parameters. ► Marcus-Hush does not always enable satisfactory fitting of experimental voltammetry.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics Letters - Volume 517, Issues 1–3, 28 November 2011, Pages 29-35
نویسندگان
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