Enantiodiscrimination and extraction of short and long range homo- and hetero-nuclear residual dipolar couplings by a spin selective correlation experiment

► Chiral discrimination of molecules in chiral liquid crystalline medium. ► Precise measurement of homo and heteronuclear couplings dipolar couplings. ► Simplification of the Complex multiplet pattern. ► Demixing of the severe spectral overlap. ► Spin state selection by single 13C spin as a spy nucleus.