Electronic structures and properties of MAu and MOH, where MÂ =Â Tl and element 113

of fully relativistic DFT calculations for MAu and MOH, where M = Tl and element 113, have shown that the compounds of element 113 are stable though weaker bound than their Tl homologs. The binding energy of 113Au is indicative of a possible strong interaction of element 113 with a gold surface, with estimated ΔHads(113) of −158.6 kJ/mol. Formation of 113OH in the presence of oxygen is expected.