Structures and electron affinities of BrO2F and BrO3F

Unlike 'cousin' BrOnCl species, the BrOnF/BrOnF− (n = 2, 3) species are prone to form FBrOn/FBrOn- chains of BrF/BrF− and On/On- moieties, which favor over the Br-On-F chains or Br-centered FBrOn structures.