Theoretical studies on the reactions Cl + CH3COCCl2X (X = F, Cl, Br)

Theoretical investigations are carried out on the reactions Cl + CH3COCCl2X (X = F, Cl, Br) by means of direct dynamics method at the MC-QCISD//MP2/6-31+G(d,p) level. The rate constants are calculated by CVT with SCT correction in the temperature range 200-3000 K.