کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5391432 1505101 2008 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Excited state proton transfer in a 'super' photoacid based on a phenol-pyridinium biaryl chromophore
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Excited state proton transfer in a 'super' photoacid based on a phenol-pyridinium biaryl chromophore
چکیده انگلیسی

We report the effect of a N-methylpyridinium substituent on the photoacidity enhancement of a phenol derivative. The steady-state and time-resolved fluorescence of this new phenolic 'super' photoacid (HPPy) are measured in different solvents in comparison with its methoxy analogue (MPPy). Solvatochromic shifts and nonradiative rate constants ascribable to excited state proton transfer (ESPT) are correlated with the empirical Kamlet-Taft parameters (π*, α, and β). Whereas, spectral shift of MPPy is mainly correlated to π* parameter, HPPy is also strongly influenced by β. At 77 K, ESPT is hampered and leads to the switch 'on' emission of conjugated base.

Excited state proton transfer process in various pure solvents is investigated in a novel phenol-pyridinium biaryl chromophore

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics Letters - Volume 455, Issues 4–6, 10 April 2008, Pages 238-241
نویسندگان
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