Recoupled separated-local-field experiments and applications to study intermediate-regime molecular motions

► A new implementation of the recoupled DIPSHIFT method is proposed. ► Besides XH coupling amplification it is sensitive to motion-induced T2 effects. ► It is sensitive even when the coupling is weak or the reorientation angle is small. ► Motions with rates ranging from hundreds of Hz to around a MHz are accessible. ► The best experimental conditions to avoid imperfections are presented.