Combining dipolar-quadrupolar correlation spectroscopy with isotropic shift resolution in magic-angle-spinning 17O NMR

► Effect of recoupled dipolar coupling on satellite transition and multiple quantum transition. ► Introduction of a three dimensional pulse scheme combining DQF-STMAS and R1825 symmetry sequence. ► Extraction of quadrupolar parameters and the heteronuclear dipolar coupling with the neighbouring spin 12 nuclei. ► Estimation of the distance between the quadrupolar nuclei and the spin 12 nuclei. ► Estimation of the relative orientation of the quadrupolar tensor with respect to the dipolar tensor.