کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5406890 1393193 2009 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Defining the sampling space in multidimensional NMR experiments: What should the maximum sampling time be?
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Defining the sampling space in multidimensional NMR experiments: What should the maximum sampling time be?
چکیده انگلیسی
Efficient sampling of signals is a key issue for multiple-dimensional NMR experiments to establish the best ratio between experiment time and spectral quality. Focussing on the most widely used sampling strategy using standard rectangular sampling and data analysis by Fourier transformation, a central question is concerned with determining the optimal maximum sampling time in the individual dimensions. The spectral resolution depends directly on this choice, as do the overall experiment times when addressing the indirect dimensions. We present a theoretical, numerical, and experimental analysis of the sampling space problem and propose approaches to efficient sampling for typical cases.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetic Resonance - Volume 199, Issue 2, August 2009, Pages 146-158
نویسندگان
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