کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5407207 | 1393207 | 2008 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Fast amplitude-modulated pulse trains with frequency sweep (SW-FAM) in solid-state NMR of spin-7/2 nuclei
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
We here investigate the sensitivity enhancement of central-transition NMR spectra of quadrupolar nuclei with spin-7/2 in the solid state, generated by fast amplitude-modulated RF pulse trains with constant (FAM-I) and incremented pulse durations (SW-FAM). Considerable intensity is gained for the central-transition resonance of single-quantum spectra by means of spin population transfer from the satellite transitions, both under static and magic-angle-spinning (MAS) conditions. It is also shown that incorporation of a SW-FAM train into the excitation part of a 7QMAS sequence improves the efficiency of 7Q coherence generation, resulting in improved signal-to-noise ratio. The application of FAM-type pulse trains may thus facilitate faster spectra acquisition of spin-7/2 systems.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetic Resonance - Volume 193, Issue 1, July 2008, Pages 102-109
Journal: Journal of Magnetic Resonance - Volume 193, Issue 1, July 2008, Pages 102-109
نویسندگان
Thomas Bräuniger, P.K. Madhu,