کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5407328 | 1393212 | 2007 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Nitrogen-14 nuclear quadrupole resonance (NQR): Dramatic sensitivity enhancement by large and fast temperature lowering
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
We have observed that, when going rapidly from ambient temperature down to liquid nitrogen temperature, the nitrogen-14 NQR signal (for transitions involving the m = 0 spin state, nitrogen-14 being a quadrupolar nucleus of spin I = 1) is increased by a factor of ca. 102. While Boltzmann statistics cannot explain this enhancement, the strong temperature dependence of the quadrupolar interaction is very likely to be at the origin of this phenomenon. Indeed, the quadrupolar Hamiltonian becomes time dependent and is prone to induce transitions toward the spin state associated with m = 0. Its binding and slow relaxing properties result in a durable increased population and consequently in an increased intensity of NQR lines originating from the state m = 0.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetic Resonance - Volume 188, Issue 2, October 2007, Pages 275-278
Journal: Journal of Magnetic Resonance - Volume 188, Issue 2, October 2007, Pages 275-278
نویسندگان
Maude Ferrari, Alain Retournard, Daniel Canet,