کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5407424 | 1393216 | 2007 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Adiabatic 1H decoupling scheme for very accurate intensity measurements in 13C NMR
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Adiabatic 1H decoupling scheme for very accurate intensity measurements in 13C NMR Adiabatic 1H decoupling scheme for very accurate intensity measurements in 13C NMR](/preview/png/5407424.png)
چکیده انگلیسی
Adiabatic proton decoupling has been optimized in order to obtain accurate quantitative measurements of intensities on 13C NMR spectra. For each offset, the minimum adiabaticity factor (Km) reached during the pulse was computed. This Km profile was used to optimize the peak value and the swept frequency range of the adiabatic pulses. With a cosinus amplitude modulation, offset-independent-adiabaticity, and the M4P5-M4P9-M4P5â²-M4P9â² phase cycle, an accuracy of 2â° for the 13C NMR measurements was reached. An approach using bi-labeled 13C acetic acid and ethanol at 99% allowed a fine experimental determination of the uniformity of the decoupling profile. The comparison with WALTZ-16 highlights the improvements in the uniformity of the proton decoupling.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetic Resonance - Volume 185, Issue 1, March 2007, Pages 50-58
Journal: Journal of Magnetic Resonance - Volume 185, Issue 1, March 2007, Pages 50-58
نویسندگان
Eve Tenailleau, Serge Akoka,