کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5407495 1393219 2007 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Low temperature probe for dynamic nuclear polarization and multiple-pulse solid-state NMR
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Low temperature probe for dynamic nuclear polarization and multiple-pulse solid-state NMR
چکیده انگلیسی
Here, we describe the design and performance characteristics of a low temperature probe for dynamic nuclear polarization (DNP) experiments, which is compatible with demanding multiple-pulse experiments. The competing goals of a high-Q microwave cavity to achieve large DNP enhancements and a high efficiency NMR circuit for multiple-pulse control lead to inevitable engineering tradeoffs. We have designed two probes-one with a single-resonance RF circuit and a horn-mirror cavity configuration for the microwaves and a second with a double-resonance RF circuit and a double-horn cavity configuration. The advantage of the design is that the sample is in vacuum, the RF circuits are locally tuned, and the microwave resonator has a large internal volume that is compatible with the use of RF and gradient coils.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetic Resonance - Volume 187, Issue 2, August 2007, Pages 242-250
نویسندگان
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