کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5407529 | 1393220 | 2007 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Analyses, extensions and comparison of three experimental schemes for measuring (nJCHÂ +Â DCH)-couplings at natural abundance
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Analyses, extensions and comparison of three experimental schemes for measuring (nJCHÂ +Â DCH)-couplings at natural abundance Analyses, extensions and comparison of three experimental schemes for measuring (nJCHÂ +Â DCH)-couplings at natural abundance](/preview/png/5407529.png)
چکیده انگلیسی
Three types of experiments for measuring nJCH heteronuclear long-range coupling constants are examined and extended with state-of-the-art pulse sequence building-blocks: The use of a HMBC with corresponding reference-HSQC for accurate coupling determination is combined with the constant time technique and the conversion of antiphase magnetization into ZQ/DQ-coherences; CPMG-based LR-CAHSQC and BIRDr,X-HSQMBC experiments are examined in detail with respect to their coherence transfer properties; finally, the HSQC-TOCSY-IPAP experiment is introduced, a sequence derived from previously published α and β selective HSQC-TOCSYs using a different spin state selection technique and a recently developed ZQ-suppression method. The experiments are characterized with their advantages and disadvantages and compared using strychnine and menthol as standard molecules.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetic Resonance - Volume 186, Issue 1, May 2007, Pages 131-141
Journal: Journal of Magnetic Resonance - Volume 186, Issue 1, May 2007, Pages 131-141
نویسندگان
Kyryl Kobzar, Burkhard Luy,